Regioselectivity of Radical Additions to Substituted Alkenes: Insight from Conceptual Density Functional Theory-Reference-Cited by-同舟云学术

Regioselectivity of Radical Additions to Substituted Alkenes: Insight from Conceptual Density Functional Theory

Published:2010-07-08 Issue:15 Volume:75 Page:4964-4974
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

De Vleeschouwer Freija¹,Jaque Pablo²,Geerlings Paul¹,Toro-Labbé Alejandro³,De Proft Frank¹

Affiliation:

1. Eenheid Algemene Chemie (ALGC), Vrije Universiteit Brussel (VUB), Pleinlaan 2, 1050 Brussels, Belgium

2. Universidad Andres Bello, Facultad de Ecología y Recursos Naturales, Departamento de Ciencias Químicas, Laboratorio de Química Teórica, Av. Republica 275, Santiago, Chile

3. Laboratorio de Química Teórica Computacional (QTC), Pontificia Universidad Católica de Chile, Santiago, Chile

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo100503e

Reference46 articles.

1. The kinetics and orientation of free-radical addition to olefins

2. The importance of polarity and steric effects in determining the rate and orientation of free radical addition to olefins

3. Formation of CC Bonds by Addition of Free Radicals to Alkenes

4. Separation of polar and steric effects on absolute rate constants and arrhenius parameters for the reaction oftert-butyl radicals with alkenes

5. Absolute rate constants for the addition of hydroxymethyl radicals to alkenes in methanol solution

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