Chain propagation determines the chemo- and regioselectivity of alkyl radical additions to C–O vs. C

Chain propagation determines the chemo- and regioselectivity of alkyl radical additions to C–O vs. C–C double bonds

Published:2020 Issue:3 Volume:11 Page:731-736
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Paulisch Tiffany O.¹²³⁴,Strieth-Kalthoff Felix¹²³⁴,Henkel Christian⁵⁶⁷⁴,Pitzer Lena¹²³⁴,Guldi Dirk M.⁵⁶⁷⁴^ORCID,Glorius Frank¹²³⁴^ORCID

Affiliation:

1. Westfälische Wilhelms-Universität Münster

2. Organisch-Chemisches Institut

3. 48149 Münster

4. Germany

5. Friedrich-Alexander-Universität Erlangen-Nürnberg

6. Department of Chemistry and Pharmacy

7. 91058 Erlangen

Abstract

Reversible radical addition followed by an irreversible electron transfer leads to regio- and chemoselectivity control of radical additions to π-systems.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/C9SC04846D

Reference56 articles.

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3. Syntheses with Radicals?C?C Bond Formation via Organotin and Organomercury Compounds [New Synthetic Methods (52)]

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5. Formation of CC Bonds by Addition of Free Radicals to Alkenes

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