The Mechanism of Acceptorless Amine Double Dehydrogenation by N,N,N-Amide Ruthenium(II) Hydrides: A Combined Experimental and Computational Study-Reference-Cited by-同舟云学术

The Mechanism of Acceptorless Amine Double Dehydrogenation by N,N,N-Amide Ruthenium(II) Hydrides: A Combined Experimental and Computational Study

Published:2016-06-24 Issue:8 Volume:6 Page:4799-4813
ISSN:2155-5435
Container-title:ACS Catalysis
language:en
Short-container-title:ACS Catal.

Author:

Hale Lillian V. A.¹,Malakar Tanmay²,Tseng Kuei-Nin T.¹,Zimmerman Paul M.¹,Paul Ankan²,Szymczak Nathaniel K.¹

Affiliation:

1. Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, United States

2. Raman Center for Atomic, Molecular and Optical Sciences, Indian Association for the Cultivation of Science, Kolkata 700 032, India

Funder

Division of Chemistry

Alfred P. Sloan Foundation

Camille and Henry Dreyfus Foundation

American Chemical Society Petroleum Research Fund

Raman Center for Atomic, Molecular and Optical Sciences

Publisher

American Chemical Society (ACS)

Subject

Catalysis,General Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acscatal.6b01465

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3. bPollak, P.; Romeder, G.; Hagedorn, F.; Gelbke, H.P.InUllmann’s Encyclopedia of Industrial Chemistry,6th ed.Bailey, J. E., Eds.Wiley-VCH Verlag GmbH & Co. KGaA:Weinheim, 2000; pp252−265.

4. Catalytic coupling of nitriles with amines to selectively form imines under mild hydrogen pressure

5. Reduction of Nitriles to Amines with H 2 Catalyzed by Nonclassical Ruthenium Hydrides – Water‐Promoted Selectivity for Primary Amines and Mechanistic Investigations

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