Harnessing the Elusive 1,4-Reduction of Vinyl Epoxides through Copper Catalysis
Author:
Affiliation:
1. Organic Chemistry Department, Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, 28049 Madrid, Spain
Funder
Secretar?a de Estado de Investigaci?n, Desarrollo e Innovaci?n
FP7 Ideas: European Research Council
Publisher
American Chemical Society (ACS)
Subject
Catalysis,General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acscatal.9b02005
Reference45 articles.
1. Regio- and Stereoselective Ring Opening of Allylic Epoxides
2. Vinyl Epoxides in Organic Synthesis
3. Stereoselective Ring Expansion of Vinyl Oxiranes: Mechanistic Insights and Natural Product Total Synthesis
4. Mechanism and the Origins of Stereospecificity in Copper-Catalyzed Ring Expansion of Vinyl Oxiranes: A Traceless Dual Transition-Metal-Mediated Process
5. Redox-Triggered C–C Coupling of Alcohols and Vinyl Epoxides: Diastereo- and Enantioselective Formation of All-Carbon Quaternary Centers via tert-(Hydroxy)-Prenylation
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