Alkene insertion enables ring-opening of vinyl epoxides: a theoretical perspective-Reference-Cited by-同舟云学术

Alkene insertion enables ring-opening of vinyl epoxides: a theoretical perspective

Published:2024 Issue:17 Volume:11 Page:4730-4739
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Liu Jiabin¹,Yang Kai¹,Liu Jiying¹,Fu Dongmin¹,Li Shi-Jun¹²^ORCID,Zhang Wenjing¹^ORCID,Lan Yu¹³²^ORCID

Affiliation:

1. Green Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou, Henan 450001, China

2. State Key Laboratory of Antiviral Drugs, Pingyuan Laboratory, Xinxiang, Henan, 453007, China

3. School of Chemistry and Chemical Engineering, and Chongqing Key Laboratory of Theoretical and Computational Chemistry, Chongqing University, Chongqing 400030, China

Abstract

This mechanistic study on the Cu-catalyzed ring-opening of vinyl epoxides provides valuable insights into the mechanism for vinyl epoxide transformation and the essential roles of the copper catalyst.

Funder

National Natural Science Foundation of China

Ministry of Science and Technology of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00950A

Reference70 articles.

1. Vinyl Epoxides in Organic Synthesis

2. Asymmetric Redox Allylic Alkylation to Access 3,3′‐Disubstituted Oxindoles Enabled by Ni/NHC Cooperative Catalysis

3. Chiral Phosphoric Acid Catalyzed Conversion of Epoxides into Thiiranes: Mechanism, Stereochemical Model, and New Catalyst Design

4. Probing the Biology of Natural Products: Molecular Editing by Diverted Total Synthesis

5. Utilization of Molybdenum- and Palladium-Catayzed Dynamic Kinetic Asymmetric Transformations for the Preparation of Tertiary and Quaternary Stereogenic Centers: A Concise Synthesis of Tipranavir