Mechanism of Regioselective Ring-Opening Reactions of 1,2-Epoxyoctane Catalyzed by Tris(pentafluorophenyl)borane: A Combined Experimental, Density Functional Theory, and Microkinetic Study-Reference-Cited by-同舟云学术

Mechanism of Regioselective Ring-Opening Reactions of 1,2-Epoxyoctane Catalyzed by Tris(pentafluorophenyl)borane: A Combined Experimental, Density Functional Theory, and Microkinetic Study

Published:2018-10-09 Issue:12 Volume:8 Page:11119-11133
ISSN:2155-5435
Container-title:ACS Catalysis
language:en
Short-container-title:ACS Catal.

Author:

Yu Ying¹,Zhu Youlong²,Bhagat Mihir N.¹,Raghuraman Arjun³^ORCID,Hirsekorn Kurt F.³,Notestein Justin M.¹^ORCID,Nguyen SonBinh T.²^ORCID,Broadbelt Linda J.¹^ORCID

Affiliation:

1. Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States

2. Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States

3. The Dow Chemical Company, Lake Jackson, Texas 77566, United States

Funder

Dow Chemical Company

Publisher

American Chemical Society (ACS)

Subject

Catalysis,General Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acscatal.8b02632

Reference48 articles.

1. Sequential DMC/FAB-Catalyzed Alkoxylation toward High Primary Hydroxyl, High Molecular Weight Polyether Polyols

2. Polymerization of Ethylene Oxide, Propylene Oxide, and Other Alkylene Oxides: Synthesis, Novel Polymer Architectures, and Bioconjugation

3. Highly efficient cleavage of epoxides catalyzed by B(C6F5)3

4. Satake, M. U. Polyoxyalkylenepolyols and Process for Producing Ring-Opened Polymer. US Patent 6531566 B1, March 11, 2003.

5. Nakaminami, H.; Sugahara, S.; Yasuhara, S.; Murata, K. U. Polyoxyalkylene Polyol or Monool and Polyurethane Resin. US Patent 20120016049 A1, January 19, 2012.

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