From Aggregates to Clusters. Facile Formation of Hetero-Metal−Metal Bonds through Reductive Desulfurization by CO in a Decapacitative Transformation of a {Pt2MS2} Tbp Frame to a {Pt2MS} Tetrahedral Core (M = Ag, Cu, and Ru)-Reference-Cited by-同舟云学术

From Aggregates to Clusters. Facile Formation of Hetero-Metal−Metal Bonds through Reductive Desulfurization by CO in a Decapacitative Transformation of a {Pt2MS2} Tbp Frame to a {Pt2MS} Tetrahedral Core (M = Ag, Cu, and Ru)

Published:1997-11-01 Issue:45 Volume:119 Page:11006-11011
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Liu Huang¹,Tan Agnes L.¹,Mok K. F.¹,Mak Thomas C. W.¹,Batsanov Andrei S.¹,Howard Judith A. K.¹,Hor T. S. Andy¹

Affiliation:

1. Contribution from the Departments of Chemistry and Computational Science, Faculty of Science, National University of Singapore, Kent Ridge, Singapore 119260, the Department of Chemistry, The Chinese University of Hong Kong, Shatin, N. T., Hong Kong, and the Department of Chemistry, University of Durham, Durham DH1 3LE, U.K.

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja9718376

Reference32 articles.

1. X-Ray photoelectron spectroscopic characterization of [{Pt(PPh3)2(µ3-S)}2PtCl2], [{Pt2(PPh3)4(µ3-S)2Cu}2(µ-dppf)][PF6]2[dppf = Fe (C5H4PPh2)2] and other heterometallic aggregates derived from [{Pt(PPh3)2(µ-S)}2]

2. Heterometallic complexes of platinum with bridging sulphido- ligands: crystal structure of [{Pt2(µ-S)2(PPh3)4}2Pd](BF4)2

3. Synthesis and characterisation of [Ag2Pt4(μ-S)4(PPh3)8](BF4)2 · 0.25CHCl3

4. Chemistry of platinum sulphido-complexes. Part 5. Synthesis and crystal and molecular structure of 3-(η-cyclo-octa-1,5-diene)bis(µ3-sulphido)-1,1,2,2-tetrakis(triphenylphosphine)diplatinum(II)rhodium(I) hexafluorophosphate–dichloromethane (1/1), [Pt2Rh(µ3-S)2(PPh3)4(η-C8H12)]PF6·CH2Cl2

5. Heterometallic Pt-Au complexes with μ-3 S bridging. Syntheses and structures of Pt2 (PPh3)4(μ-SAuCl)2·2CH2Cl2 and Pt2(PPh3)4−(μ-S)(μ-SAuPPh3)NO3·0.5H2O

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