Polydentate chalcogen reagents for the facile preparation of Pd2 and Pd4 complexes
Author:
Affiliation:
1. Department of Chemistry
2. The University of Western Ontario
3. London
4. Canada
5. Centre for Advanced Materials and Biomaterials Research
Abstract
The reagent 1,2,4,5-(Me3SiSCH2)4C6H2 can be used for a facile route to the tetra-palladium tetra-thiolate complex [(dppp)4Pd4-μ-κ4S-{1,2,4,5-(SCH2)4C6H2}]4+, illustrated (dppp = 1,3-bis(diphenylphosphino)propane).
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00197H
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5. Synthesis, photophysics and electrochemistry of a novel luminescent platinum(II) sulfido complex. Crystal structure of [Pt2(µ-S)(µ-dppm)(dppm)2]2+(dppm = Ph2PCH2PPh2)
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