Interfacial Free Volume and Vitrification: Reduction in Tg in Proximity of an Adsorbing Interface Explained by the Free Volume Holes Diffusion Model-Reference-Cited by-同舟云学术

Interfacial Free Volume and Vitrification: Reduction in Tg in Proximity of an Adsorbing Interface Explained by the Free Volume Holes Diffusion Model

Published:2013-09-26 Issue:19 Volume:46 Page:8051-8053
ISSN:0024-9297
Container-title:Macromolecules
language:en
Short-container-title:Macromolecules

Author:

Napolitano Simone¹,Cangialosi Daniele²

Affiliation:

1. Laboratory of Polymer and Soft Matter Dynamics, Faculté des Sciences, Université Libre de Bruxelles, Boulevard du Triomphe, Bâtiment NO, Bruxelles 1050, Belgium

2. Centro de Física de Materiales (CSIC-UPV/EHU), Paseo Manuel de Lardizabal 5, 20018 San Sebastián, Spain

Publisher

American Chemical Society (ACS)

Subject

Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ma401368p

Reference44 articles.

1. Free Surfaces Cause Reductions in the Glass Transition Temperature of Thin Polystyrene Films

2. Measuring the Surface Dynamics of Glassy Polymers

3. Substrate and Chain Size Dependence of Near Surface Dynamics of Glassy Polymers

4. Structural Relaxation of Polymer Glasses at Surfaces, Interfaces, and In Between

5. The lifetime of the deviations from bulk behaviour in polymers confined at the nanoscale

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