Intrinsic Barriers in Identity SN2 Reactions and the Periodic Table-Reference-Cited by-同舟云学术

Intrinsic Barriers in Identity SN2 Reactions and the Periodic Table

Published:1999-08-01 Issue:33 Volume:121 Page:7724-7725
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Hoz Shmaryahu¹,Basch Harold¹,Wolk Joel L.¹,Hoz Tova¹,Rozental Esther¹

Affiliation:

1. Department of Chemistry, Bar-Ilan University Ramat-Gan, Israel 52900

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja984315e

Reference11 articles.

1. Chemical and Electrochemical Electron-Transfer Theory

2. Reactivity of Strained Compounds: Is Ground State Destabilization the Major Cause for Rate Enhancement?1

3. The preliminary results for the intrinsic barrier height were obtained for a smaller set of reactions at the RHF/6-31+G* theory level. They showed the same column dependence described in this paper for the G2(+) level reaction barriers but with higher values, as is to be expected.

4. Gas-Phase Identity SN2 Reactions of Halide Anions with Methyl Halides: A High-Level Computational Study

5. Extension of Gaussian‐2 (G2) theory to bromine‐ and iodine‐containing molecules: Use of effective core potentials

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