Mechanism of the [RhF(PPh3)3] to cis-[RhPh(PPh3)2(PFPh2)] Interconversion: P−C Activation and F/Ph Exchange via a Metallophosphorane Pathway
Author:
Affiliation:
1. School of Engineering and Physical Sciences, William Perkin Building, Heriot-Watt University, Edinburgh EH14 4AS, U.K.
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om0610703
Reference49 articles.
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3. Transition-metal-mediated phosphorus-carbon bond cleavage and its relevance to homogeneous catalyst deactivation
4. The migration and cleavage of substituents from donor atoms in coordination compounds of the transition metals
5. Transition metal-mediated P–C/X exchange at bound phosphine ligands (X = aryl, alkyl, NR2, OR and F): scope and mechanisms
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