Synthesis and reductive elimination of arylPd(ii) trifluoromethyl complexes: a remarkable concentration effect on chemoselectivity
Author:
Affiliation:
1. The Key Laboratory of Food Colloids and Biotechnology
2. Ministry of Education
3. School of Chemical and Material Engineering
4. Jiangnan University
5. Wuxi 214122
Abstract
A remarkable and unprecedented concentration effect on chemoselectivity is observed for the thermal decomposition of Pd(ii) aryl trifluoromethyl complexes. As the concentration increases, the Ar–CF3 cross-coupling is suppressed gradually whilst the Ar–Ar homocoupling increases steadily.
Funder
National Natural Science Foundation of Jiangsu Province
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP07093K
Reference34 articles.
1. P. Kirsch , Modern Fluoroorganic Chemistry, Wiley-VCH, Weinheim, Germany, 2004
2. Fluorine in medicinal chemistry
3. Redox potentials of trifluoromethyl-containing compounds
4. CF3-Bearing Aromatic and Heterocyclic Building Blocks
5. Update 1 of: Asymmetric Fluorination, Trifluoromethylation, and Perfluoroalkylation Reactions
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