A Versatile and Highly Selective Hypervalent Iodine (III)/2,2,6,6-Tetramethyl-1-piperidinyloxyl-Mediated Oxidation of Alcohols to Carbonyl Compounds
Author:
Affiliation:
1. Centro CNR di Studio per la Chimica delle Sostanze Organiche Naturali, Istituto Nazionale di Coordinamento “Chimica dei Sistemi Biologici”, and Dipartimento di Chimica, Università “La Sapienza”, Piazzale Aldo Moro 5, 00185 Roma, Italy
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo971046m
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1. Readily accessible 12-I-5 oxidant for the conversion of primary and secondary alcohols to aldehydes and ketones
2. A useful 12-I-5 triacetoxyperiodinane (the Dess-Martin periodinane) for the selective oxidation of primary or secondary alcohols and a variety of related 12-I-5 species
3. An improved procedure for the preparation of the Dess-Martin periodinane
4. Acceleration of the Dess-Martin Oxidation by Water
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