Isotope Effect, Mechanism, and Origin of Catalysis in the Decarboxylation of Mandelylthiamin
Author:
Affiliation:
1. Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas 77842
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja101775s
Reference18 articles.
1. Making Thiamin Work Faster: Acid-Promoted Separation of Carbon Dioxide
2. Accelerating Unimolecular Decarboxylation by Preassociated Acid Catalysis in Thiamin-Derived Intermediates: Implicating Brønsted Acids as Carbanion Traps in Enzymes
3. Internal Return of Carbon Dioxide in Decarboxylation: Catalysis of Separation and 12C/13C Kinetic Isotope Effects
4. Thiamin Diphosphate Catalysis: Enzymic and Nonenzymic Covalent Intermediates
5. Catalyzing separation of carbon dioxide in thiamin diphosphate-promoted decarboxylation
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