Intermolecular Alkynyl Ligand Transfer in Palladium(II) and Platinum(II) Complexes with −C⋮CCOOR and −C⋮CPh Ligands. Relative Stability of the Alkynyl Complexes and Conproportionation of Dialkynyl and Diiodo Complexes of These Metals

Author:

Osakada Kohtaro1,Hamada Makiko1,Yamamoto Takakazu1

Affiliation:

1. Research Laboratory of Resources Utilization, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference61 articles.

1. Review articles:  (a) Carruthers W. InComprehensive OrganometallicChemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon:  New York, 1982; Vol. 7, pp 722−724. (b) Lipshutz, B. H. InOrganometallicsin Synthesis. A Manual; Schlosser, M., Ed.; John Wiley:  Chichester, 1994; pp 300−302, and references therein. (c) Heck, R. F. Palladium Reagents inOrganic Synthesis; Academic Press:  London, 1985; p 299. (d) Sonogashira, K.; Takahashi, S.J. Synth. Org. Chem. Jap.1993,51, 1053 (in Japanese).

2. A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridines

3. A Convenient Synthesis of Ethynylarenes and Diethynylarenes

4. A convenient synthesis of 4-ethynylphthalic anhydride via 2-methyl-3-butyn-2-ol

5. Synthesis of arylacetylenes by the sodium hydride catalyzed cleavage of 4-aryl-2-methyl-3-butyn-2-ols

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