Regular and Inverse Secondary Kinetic Enthalpy Effects (KHE) for the Rate of Inversion of Thioether and 1,1‘-Biisoquinoline Complexes of Ruthenium and Osmium
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, The University of Oklahoma, 620 Parrington Oval, Rm. 208, Norman, Oklahoma 73019
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic0105720
Reference56 articles.
1. Kinetics and mechanism of the facile diastereomeric isomerization of a tris(bidentate)ruthenium(II) complex bearing a misdirected bipyridyl ligand: .DELTA...LAMBDA.-(.delta./.lambda.-1,1'-biisoquinoline)bis(2,2'-bipyridine)ruthenium(II)
2. Metal-Assisted Racemization of the Atropisomers of a 1,1'-Binaphthyl Skeleton via a Syn Transition State
3. Inverse Relationship between the Kinetic and Thermodynamic Stabilities of the Misdirected Ligand Complexes .DELTA./.LAMBDA.-(.delta./.lambda.-1,1'-Biisoquinoline)bis(2,2'-bipyridine)metal(II) (metal = Ruthenium, Osmium)
4. Kinetic Element Effect for Atropisomerization of an Organometallic Complex of the Misdirected Ligand 1,1‘-Biisoquinoline
5. Organometallic bond dissociation energies: laser pyrolysis of iron pentacarbonyl, chromium hexacarbonyl, molybdenum hexacarbonyl, and tungsten hexacarbonyl
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