Polyhedral Flexibility in the Sulfido-Capped Cluster H2Ru3(CO)9(μ3-S) on Reaction with 2-(Diphenylphosphino)thioanisole (PS) and Reversible Tripodal Rotation of the Chelated PS Ligand in H2Ru3(CO)7(κ2-PS)(μ3-S)
Author:
Affiliation:
1. Department of Chemistry, University of North Texas, Denton, Texas 76203, United States
Funder
The Robert A. Welch Foundation
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.9b00202
Reference59 articles.
1. Synthesis and Characterization of Triosmium Clusters Containing the Bidentate Ligand Ph2PCH2CH2SMe: Detection of an Isomerization Reaction Involving Bridging and Chelating Ligand Coordination Modes
2. DFT Investigation of the Mechanism of Phosphine-Thioether Isomerization in the Triosmium Cluster Os3(CO)10(Ph2PCH2CH2SMe): Migratory Preference for the Formation of an Edge-Bridged Thioether versus a Phosphine Moiety
3. Synthesis, Characterization, and Novel Fluxional Mechanisms of Triosmium Clusters Containing the Highly Flexible Ligand Ph2PC2H4SC2H4SC2H4PPh2 (PSSP)
4. Synthesis, Characterization, and Dynamic Behaviour of Triosmium Clusters Containing the Tridentate Ligand {Ph 2 PCH 2 CH 2 } 2 S (PSP)
5. Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis
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1. Synthesis and Characterization of the New Cluster Complex {Mo3S4} with the Hemilabile Phosphine-Selenoether Ligand;Russian Journal of Coordination Chemistry;2021-03
2. Trinuclear M3S4 cluster complexes with hemilabile phosphino-thioether ligands: Some experimental and theoretical aspects;Inorganica Chimica Acta;2020-08
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