1. Department of Soil Science, Federal University of Rio Grande do Sul, Avenida Bento Gonçalves 7712, 91540-000 Porto Alegre, RS, Brazil
2. Forschungszentrum Jülich GmbH, Institute of Chemistry and Dynamics of the Geosphere, ICG-4 - Agrosphere, 52425 Jülich, Germany
3. Institute of Chemistry, Federal University of Rio Grande do Sul, Avenida Bento Gonçalves 9500, 91501-970 Porto Alegre, RS, Brazil