Modeling the Peroxide/Superoxide Continuum in 1:1 Side-on Adducts of O2 with Cu
Author:
Affiliation:
1. Department of Chemistry and Supercomputer Institute, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic049958b
Reference17 articles.
1. Variable character of O--O and M--O bonding in side-on ( 2) 1:1 metal complexes of O2
2. β-Diketiminate Ligand Backbone Structural Effects on Cu(I)/O2 Reactivity: Unique Copper−Superoxo and Bis(μ-oxo) Complexes
3. Snapshots of Dioxygen Activation by Copper: The Structure of a 1:1 Cu/O2 Adduct and Its Use in Syntheses of Asymmetric Bis(μ-oxo) Complexes
4. A Monomeric Side-On Superoxocopper(II) Complex: Cu(O2)(HB(3-tBu-5-iPrpz)3)
5. Spectroscopic and Electronic Structure Studies of the Diamagnetic Side-On CuII-Superoxo Complex Cu(O2)[HB(3-R-5-iPrpz)3]: Antiferromagnetic Coupling versus Covalent Delocalization
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