Re-evaluating the Cu K pre-edge XAS transition in complexes with covalent metal–ligand interactions
Author:
Affiliation:
1. Max Planck Institute for Chemical Energy Conversion
2. 45470 Mülheim an der Ruhr
3. Germany
4. Department of Chemistry
5. Georgetown University
6. USA
7. Department of Chemistry and Chemical Biology
8. Cornell University
Abstract
Covalent metal–ligand interactions can lead to Cu K pre-edge transitions that result from metal-to-ligand charge transfer, instead of 1s → 3d, character.
Funder
Biological and Environmental Research
Max-Planck-Gesellschaft
Division of Chemistry
National Center for Research Resources
Basic Energy Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC03294B
Reference57 articles.
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2. Mononuclear Cu–O2 Complexes: Geometries, Spectroscopic Properties, Electronic Structures, and Reactivity
3. β-Diketiminate Ligand Backbone Structural Effects on Cu(I)/O2 Reactivity: Unique Copper−Superoxo and Bis(μ-oxo) Complexes
4. Snapshots of Dioxygen Activation by Copper: The Structure of a 1:1 Cu/O2 Adduct and Its Use in Syntheses of Asymmetric Bis(μ-oxo) Complexes
5. X-ray Absorption Edge Spectroscopy and Computational Studies on LCuO2 Species: Superoxide−CuII versus Peroxide−CuIII Bonding
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