Origin of Stereoselectivity in the (4 + 3) Cycloadditions of Chiral Alkoxy Siloxyallyl Cations with Furan
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, and Department of Chemistry, University of Missouri—Columbia, Columbia, Missouri 65211
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol902591k
Reference18 articles.
1. The Cycloaddition of Allyl Cations to 1,3-Dienes: General Method for the Synthesis of Seven-Membered Carbocycles. New Synthetic Methods(40)
2. Cycloaddition reactions of vinyl oxocarbenium ions
3. Ambiphilic reactivity of 1,1-dimethoxyacetone
4. Chiral Allyl Cations in Cycloadditions to Furan: Synthesis of 2-(1′-Phenylethoxy)-8-oxabicyclo[3.2.1]oct-6-en-3-one in High Enantiomeric Purity
5. Chiral Allyl Cations Are Captured by Furan with 100 % Stereoselectivity: Synthesis of Enantiopure 2-Alkoxy-8-oxabicyclo[3.2.1]oct-6-en-3-ones by Low-Temperature [4+3] Cycloaddition
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