An induced-fit model for asymmetric organocatalytic reactions: a case study of the activation of olefins <i>via</i> chiral Brønsted acid catalysts-Reference-Cited by-同舟云学术

An induced-fit model for asymmetric organocatalytic reactions: a case study of the activation of olefins via chiral Brønsted acid catalysts

Published:2022 Issue:30 Volume:13 Page:8848-8859
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Harden Ingolf¹^ORCID,Neese Frank¹^ORCID,Bistoni Giovanni¹²^ORCID

Affiliation:

1. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm Platz 1, 45470 Mülheim an der Ruhr, Germany

2. Department of Chemistry, Biology and Biotechnology, University of Perugia Via Elce di Sotto, 8, 06123 Perugia, Italy

Abstract

We elucidate the stereo-controlling factors of the asymmetric intramolecular hydroalkoxylation of terminal olefins catalyzed by bulky Brønsted acids [Science2018, 359 (6383), 1501–1505] using high-level electronic structure methods.

Funder

Max-Planck-Gesellschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC02274E

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