Modeling and Experiment Reveal an Unexpected Stereoelectronic Effect on Conformation and Scalar Couplings of α-Aminoorganostannanes, with Possible Relevance to the Tin−Lithium Exchange Reaction
Author:
Affiliation:
1. Department of Chemistry, University of Miami, Coral Gables, Florida 33124, and Department of Chemistry and Biochemistry, University of Arkansas, Fayetteville, Arkansas 72701
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo034948y
Reference38 articles.
1. (a) Clayden, J.Organolithiums: Selectivity for Synthesis; Pergamon: 2002; Vol. 23.
2. Organolithiums in Enantioselective Synthesis
3. (c) Rappoport, Z., Marek, I., Eds.The Chemistry of Organolithium Compounds; Wiley: New York, 2003.
4. Search for configurationally stable, aracemic α-amino organolithiums
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