An optical test to unveil twisting of birefringent crystals in spherulites

Abstract

Helical conformations and structures are frequently observed in materials. The presence of helices at points of the unit cell of a crystal, on a larger size scale in the crystalline lattice or even in the microscopic structure of crystals, affects the chemico-physical properties of a solid and, hence, also interactions with light. Here, attention has been drawn to the geometrical properties of helices produced by a hypothetical torque of a transparent crystal, and optical properties of twisted crystals easily observed by a polarizing microscope have been discussed. Radially grown spherulites are obtained by most substances crystallized from melt. The circular arrangement of elongated crystals reflects the optical behaviour of each crystal and, because of the larger dimensions of spherulites, allows investigations otherwise hardly feasible on separate crystals. According to the torsional analysis of elongated bodies and the birefringence theory, information on the existence of helically shaped crystals can be deduced, as hereinafter explained, from the microscopic appearance and birefringence pattern of spherulites. Indeed, twisting decreases the birefringence throughout an elongated crystal and, therefore, also the birefringence of spherulites formed by twisted radial crystals is reduced.