Abstract
A new calorimeter, suitable for the measurement of heats of mixing as small as 0·1 J resulting from the mixing of not more than 1cm
3
of each component in the absence of any vapour phase and over a wide range of temperatures, is described. It has been used to measure heats of mixing for the pairs of liquids carbon tetrachloride + chloroform, carbon tetrachloride +
cyclo
hexane, and benzene + solutions of biphenyl in benzene. The results are examined in the light of current theories of solutions.
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