Estimation of the Standard Heat Capacity of Crystalline Alkali Metal Borates-Reference-Cited by-同舟云学术

Estimation of the Standard Heat Capacity of Crystalline Alkali Metal Borates

Published:2023-05-01 Issue:5 Volume:68 Page:630-637
ISSN:0044-457X
Container-title:Журнал неорганической химии
language:
Short-container-title:Žurnal neorganičeskoj himii

Author:

Tupitsin A. A.¹²,Yas’ko S. V,³,Bychinskii V. A.¹,Fomichev S. V.⁴,Shiribazarova E. B.⁵,Koroleva O. N.⁶

Affiliation:

1. Vinogradov Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences

2. South Urals Federal Research Center of Mineralogy and Geoecology, Ural Branch, Russian Academy of Sciences, territory Ilmen reserve

3. Irkutsk State University of Railway Engineering

4. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

5. South Ural Federal Research Center for Mineralogy and Geoecology, Ural Branch, Russian Academy of Sciences

6. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences

Abstract

A structure–property correlation was developed that makes it possible to choose the optimal values of the standard heat capacity of alkali metal borates, for which, according to the data of various experimental works and reference publications, wide variations are observed. This correlation enables one to estimate the standard heat capacity of unstudied alkali metal borates with sufficient validity. To ensure the reliability of the correlation, a critical analysis was made of the initial data taken from reference publications and original experimental works. Our own processing of experimental measurements of the heat capacity and the enthalpy increment was performed to verify the reliability of the literature values of the standard heat capacity of alkali metal borates.

Publisher

The Russian Academy of Sciences

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