Evaluation of the Standard Entropy of Crystalline Alkali Metal Borates-Reference-Cited by-同舟云学术

Evaluation of the Standard Entropy of Crystalline Alkali Metal Borates

Published:2023-12-01 Issue:12 Volume:68 Page:1762-1768
ISSN:0044-457X
Container-title:Журнал неорганической химии
language:
Short-container-title:Žurnal neorganičeskoj himii

Author:

Tupitsin A. A.¹²,Yas’ko S. V,³,Bychinskii V. A.¹,Koroleva O. N.²,Fomichev S. V.⁴

Affiliation:

1. Vinogradov Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences

2. South Urals Federal Research Center of Mineralogy and Geoecology, Ural Branch, Russian Academy of Sciences, territory Ilmen reserve

3. Irkutsk State University of Railway Engineering

4. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Abstract

A composition–property relationship has been developed that makes it possible to select the optimal values of the standard entropy of alkali metal borates, for which available experimental and reference data vary in wide ranges. This relationship allows one to estimate the standard entropy of unstudied alkali metal borates with sufficient validity. To ensure the reliability of the relationship, a critical analysis of the initial data borrowed from reference books and original experimental works has been carried out. Experimental measurements of low-temperature heat capacity were processed to verify the reliability of the standard entropy values of alkali metal borates presented in the literature.

Publisher

The Russian Academy of Sciences

Reference34 articles.

1. Тупицын А.А., Бычинский В.А., Штенберг М.В. и др. // Журн. неорган. химии. 2023. Т. 68. №. 3. С. 325. https://doi.org/10.31857/S0044457X22601808

2. Latimer W.M. The Oxidation States of the Elements and their Potentials in Aqueous Solution. N.Y.: Prentice-Hall inc., 1938. 352 p.

3. Jenkins H.D.B. // J. Chem. Thermodyn. 2020. V. 144. P. 106052. https://doi.org/10.1016/j.jct.2020.106052

4. Тупицын А.А., Ясько С.В., Бычинский В.А. и др. // Журн. неорган. химии. 2023. Т. 68. № 5. С. 630. https://doi.org/10.31857/S0044457X22602267

5. Jenkins H.D.B. // J. Chem. Thermodyn. 2019. V. 135. P. 278. https://doi.org/10.1016/j.jct.2019.03.013