Template Synthesis of the Trinuclear Cobalt(III) Complex with Diarylimidazole-Based Ligands: Synthesis and Properties-Reference-Cited by-同舟云学术

Template Synthesis of the Trinuclear Cobalt(III) Complex with Diarylimidazole-Based Ligands: Synthesis and Properties

Published:2023-06-01 Issue:6 Volume:49 Page:360-366
ISSN:0132-344X
Container-title:Координационная химия
language:
Short-container-title:Koordinacionnaâ himiâ

Author:

Nikovskii I. A.¹²,Karnaukh K. M.³,Aliev T. M.¹,Polezhaev A. V.¹²,Spiridonov K. A.¹⁴,Dan’shina A. A.¹⁵,Nelyubina Yu. V.¹²,Novikov V. V.¹²

Affiliation:

1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

2. Bauman State Technical University, Moscow, Russia

3. University of California, 93106, Santa Barbara, California, USA

4. Moscow State University, Moscow, Russia

5. Moscow Institute of Physics and Technology (National Research University), Dolgoprudnyi, Moscow oblast, Russia

Abstract

The trinuclear cobalt(III) complex [(Bipy)5Co3(L)2](Cl)3 (I) is synthesized by the template reaction of 2,2'-(1H-imidazole-4,5-diyl)bis(4-ethylphenol) (L) and bis(2,2-bipyridine)cobalt(II) dichloride in the presence of diazabicycloundecene. The complex is isolated in the individual state and characterized by elemental analysis, cyclic voltammetry, UV-VIS spectroscopy, and X-ray diffraction (XRD) (CIF file СCDC no. 2201135). According to the obtained data, the cobalt ions in trinuclear complex I have the oxidation state +3, and the complex formation occurs with the oxidation of the initial cobalt(II) ions.

Publisher

The Russian Academy of Sciences

Reference27 articles.

1. Evangelio E., Ruiz-Molina D. // Eur. J. Inorg. Chem. 2005. V. 2005. P. 2957.

2. Gütlich P., Garcia Y., Woike T. // Coord. Chem. Rev. 2001. V. 219–221. P. 839.

3. Tezgerevska T., Rousset E., Gable R.W. et al. // Dalton Trans. 2019. V. 48. P. 11674.

4. Rajput A., Sharma A.K., Barman S.K. et al. // Coord. Chem. Rev. 2020. V. 414. P. 213240.

5. Slater J.W., D’Alessandro, D.M., Keene, F.R. et al. // Dalton Trans. 2006. V. 0. P. 1954.