Author:
Sanz Alejandro,Linares Amelia,García-Gutiérrez Mari Cruz,Nogales Aurora,Paszkiewicz Sandra,Zubkiewicz Agata,Szymczyk Anna,Ezquerra Tiberio A.
Abstract
This article presents an experimental study on the relaxation dynamics of a series of random copolymers based on bio-friendly comonomers with interesting gas barrier properties. We analyze the relaxation response in the glassy and ultraviscous regime of poly (trimethylene furanoate/sebacate) random copolymers via dielectric spectroscopy. We report lower values of dynamic fragility [a dimensionless index introduced in 1985 (Angell, Relaxations in Complex Systems, 1985)] in comparison to popular polyesters widely used in industry, such as poly (ethylene terephthalate), suggesting that the amorphous phase of these furanoate-based polyesters adopt an efficient chain packing. This is consistent with their low permeability to gases. We also discuss on different equations (phenomenological and theory-based approaches) for fitting the temperature-evolution of the alpha relaxation time.
Funder
Agencia Estatal de Investigación
Narodowym Centrum Nauki
European Commission
Cited by
1 articles.
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