Supramolecular structure, relaxation behavior and free volume of bio-based poly(butylene 2,5-furandicarboxylate)-block-poly(caprolactone) copolyesters

Author:

Paszkiewicz Sandra1ORCID,Irska Izabela1,Zubkiewicz Agata2,Walkowiak Konrad1,Rozwadowski Zbigniew3,Dryzek Jerzy4,Linares Amelia5,Nogales Aurora5ORCID,Ezquerra Tiberio A.5ORCID

Affiliation:

1. Department of Materials Technologies, West Pomeranian University of Technology, Al. Piastow 19, PL-70310 Szczecin, Poland

2. Department of Physics, West Pomeranian University of Technology, Al. Piastow 48, PL-70311 Szczecin, Poland

3. Department of Inorganic and Analytical Chemistry, West Pomeranian University of Technology, Al. Piastów 42, PL-71065 Szczecin, Poland

4. Institute of Nuclear Physics PAS, ul. Radzikowskiego 152, PL-31342 Cracow, Poland

5. Instituto de Estructura de la Materia, IEM-CSIC, Serrano 121, Madrid 28006, Spain

Abstract

A fully plant-based sustainable copolyester series, poly(butylene 2,5-furandicarboxylate)-block-poly(caprolactone)s, were successfully synthesized by melt polycondensation combining butylene 2,5-furandicarboxylate with polycaprolactone diol at different weight ratios.

Funder

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

Reference87 articles.

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