Recent Progress and Perspective: Na Ion Batteries Used at Low Temperatures

Abstract

With the rapid development of electric power, lithium materials, as a rare metal material, will be used up in 50 years. Sodium, in the same main group as lithium in the periodic table, is abundant in earth’s surface. However, in the study of sodium-ion batteries, there are still problems with their low-temperature performance. Its influencing factors mainly include three parts: cathode material, anode material, and electrolyte. In the cathode, there are Prussian blue and Prussian blue analogues, layered oxides, and polyanionic-type cathodes in four parts, as this paper discusses. However, in the anode, there is hard carbon, amorphous selenium, metal selenides, and the NaTi2(PO4)3 anode. Then, we divide the electrolyte into four parts: organic electrolytes; ionic liquid electrolytes; aqueous electrolytes; and solid-state electrolytes. Here, we aim to find electrode materials with a high specific capacity of charge and discharge at lower temperatures. Meanwhile, high-electrical-potential cathode materials and low-potential anode materials are also found. Furthermore, their stability in air and performance degradation in full cells and half-cells are analyzed. As for the electrolyte, despite the aspects mentioned above, its electrical conductivity in low temperatures is also reported.