Effects of Nd2O3 Nanoparticles on the Structural Characteristics and Dielectric Properties of PVA Polymeric Films

Author:

Alshammari Khulaif1ORCID,Alashgai Thamer1,Alshammari Alhulw H.1ORCID,Abdelhamied Mostufa M.2,Alotibi Satam3ORCID,Atta Ali1ORCID

Affiliation:

1. Physics Department, College of Science, Jouf University, P.O. Box 2014, Sakaka 72388, Saudi Arabia

2. Charged Particles Lab., Radiation Physics Department, National Center for Radiation Research and Technology (NCRRT), Egyptian Atomic Energy Authority (EAEA), Cairo 13759, Egypt

3. Department of Physics, College of Science and Humanities in Al-Kharj, Prince Sattam bin Abdulaziz University, Al-Kharj 11942, Saudi Arabia

Abstract

Polyvinyl alcohol (PVA) and Neodymium (III) oxide (Nd2O3) were combined to synthesized flexible innovative PVA/Nd2O3 polymer composite samples utilizing a solution casting approach for use in dielectric devices. The XRD, FTIR, and SEM methods are all investigated to characterize the composite films. In a frequency of 50 Hz to 5 MHz, the effects of additive Nd2O3 on the dielectric behavior of PVA were recorded. The PVA/Nd2O3 composite films were successfully fabricated, as shown by XRD and infrared spectroscopy. The scanning microscopy pictures showed that the Nd2O3 was loaded and distributed uniformly throughout the PVA. After the incorporation of Nd2O3, the composite PVA/Nd2O3 has a conductivity of 6.82 × 10−9 S·cm−1, while the PVA has a conductivity of 0.82 × 10−9 S·cm−1. Another improvement is the decrease in the relaxation time from 14.2 × 10−5 s for PVA to 6.35 × 10−5 s for PVA/Nd2O3, and an increase in the dielectric constant of 0.237 for PVA to 0.484 at a frequency of 100 Hz. The results showed that the composite samples have considerable changes as flexible films in different applications, including batteries and electronic circuits.

Funder

Deanship of Scientific Research at Jouf University

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

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