Response Surface Optimization on Ferrate-Assisted Coagulation Pretreatment of SDBS-Containing Strengthened Organic Wastewater

Abstract

Sodium dodecylbenzene sulfonate (SDBS), an anionic surfactant, has both hydrophilic and lipophilic properties and is widely used in daily production and life. The SDBS-containing organic wastewater is considered difficult to be degraded, which is harmful to the water environment and human health. In this study, ferrate-assisted coagulation was applied to treat SDBS wastewater. Firstly, a single-factor experiment was conducted to investigate the effect of the Na2FeO4 dosage, polyaluminum chloride (PAC) dosage, pH and temperature on the treatment efficiency of SDBS wastewater; then, a response surface optimization experiment was further applied to obtain the optimized conditions for the SDBS treatment. According to the experimental results, the optimal treatment conditions were shown as follows: the Na2FeO4 dosage was 57 mg/L, the PAC dosage was 5 g/L and pH was 8, under which the chemical oxygen demand (COD) removal rate was 90%. Adsorption bridging and entrapment in the floc structure were the main mechanisms of pollution removal. The ferrate-assisted coagulation treatment of strengthened SDBS wastewater was verified by a response surface experiment to provide fundamental understandings for the treatment of the surfactant.