Enhanced Propanol Response Behavior of ZnFe2O4 NP-Based Active Sensing Layer Induced by Film Thickness Optimization

Abstract

Development of gas sensors displaying improved sensing characteristics including sensitivity, selectivity, and stability is now possible owing to tunable surface chemistry of the sensitive layers as well as favorable transport properties. Herein, zinc ferrite (ZnFe2O4) nanoparticles (NPs) were produced using a microwave-assisted hydrothermal method. ZnFe2O4 NP sensing layer films with different thicknesses deposited on interdigitated alumina substrates were fabricated at volumes of 1.0, 1.5, 2.0, and 2.5 µL using a simple and inexpensive drop-casting technique. Successful deposition of ZnFe2O4 NP-based active sensing layer films onto alumina substrates was confirmed by X-ray diffraction and atomic force microscope analysis. Top view and cross-section observations from the scanning electron microscope revealed inter-agglomerate pores within the sensing layers. The ZnFe2O4 NP sensing layer produced at a volume of 2 μL exhibited a high response of 33 towards 40 ppm of propanol, as well as rapid response and recovery times of 11 and 59 s, respectively, at an operating temperature of 120 °C. Furthermore, all sensors demonstrated a good response towards propanol and the highest response against ethanol, methanol, carbon dioxide, carbon monoxide, and methane. The results indicate that the developed fabrication strategy is an inexpensive way to enhance sensing response without sacrificing other sensing characteristics. The produced ZnFe2O4 NP-based active sensing layers can be used for the detection of volatile organic compounds in alcoholic beverages for quality check in the food sector.