Characteristics and Sources of Volatile Organic Compounds in the Nanjing Industrial Area

Abstract

In this study, 56 volatile organic compounds species (VOCs) and other pollutants (NO, NO2, SO2, O3, CO and PM2.5) were measured in the northern suburbs of Nanjing from September 2014 to August 2015. The total volatile organic compound (TVOC) concentrations were higher in the autumn (40.6 ± 23.8 ppbv) and winter (41.1 ± 21.7 ppbv) and alkanes were the most abundant species among the VOCs (18.4 ± 10.0 ppbv). According to the positive matrix factorization (PMF) model, the VOCs were found to be from seven sources in the northern suburbs of Nanjing, including liquefied petroleum gas (LPG) sources, gasoline vehicle emissions, iron and steel industry sources, industrial refining coke sources, solvent sources and petrochemical industry sources. One of the sources was influenced by seasonal variations: it was a diesel vehicle emission source in the spring, while it was a coal combustion source in the winter. According to the conditional probability function (CPF) method, it was found that the main contribution areas of each source were located in the easterly direction (mainly residential areas, industrial areas, major traffic routes, etc.). There were also seasonal differences in concentration, ozone formation potential (OFP), OH radical loss rate (LOH) and secondary organic aerosols potential (SOAP) for each source due to the high volatility of the summer and autumn temperatures, while combustion increases in the winter. Finally, the time series of O3 and OFP was compared to that PM2.5 and SOAP and then they were combined with the wind rose figure. It was found that O3 corresponded poorly to the OFP, while PM2.5 corresponded well to the SOAP. The reason for this was that the O3 generation was influenced by several factors (NOx concentration, solar radiation and non-local transport), among which the influence of non-local transport could not be ignored.