Quantification of SO2 Emission Variations and the Corresponding Prediction Improvements Made by Assimilating Ground-Based Observations

Abstract

In this research, a new time-resolved emission inversion system was developed to investigate variations in SO2 emission in China during the COVID-19 (Corona Virus Disease 2019) lockdown period based on a four-dimensional variational (4DVar) inversion method to dynamically optimize the SO2 inventory by assimilating the ground-based hourly observation data. The inversion results obtained were validated in the North China Plain (NCP). Two sets of experiments were carried out based on the original and optimized inventories during the pre-lockdown and lockdown period to quantify the SO2 emission variations and the corresponding prediction improvement. The SO2 emission changes due to the lockdown in the NCP were quantified by the differences in the averaged optimized inventories between the pre-lockdown and lockdown period. As a response to the lockdown control, the SO2 emissions were reduced by 20.1% on average in the NCP, with ratios of 20.7% in Beijing, 20.2% in Tianjin, 26.1% in Hebei, 18.3% in Shanxi, 19.1% in Shandong, and 25.9% in Henan, respectively. These were mainly attributed to the changes caused by the heavy industry lockdown in these areas. Compared to the model performance based on the original inventory, the optimized daily SO2 emission inventory significantly improved the model SO2 predictions during the lockdown period, with the correlation coefficient (R) value increasing from 0.28 to 0.79 and the root-mean-square error (RMSE) being reduced by more than 30%. Correspondingly, the performance of PM2.5 was slightly improved, with R-value increasing from 0.67 to 0.74 and the RMSE being reduced by 8% in the meantime. These statistics indicate the good optimization ability of the time-resolved emission inversion system.