Synthesis and Characterization of Low-Cost Cresol-Based Benzoxazine Resins as Potential Binders in Abrasive Composites

Author:

Jamrozik Artur,Barczewski MateuszORCID,Framski GrzegorzORCID,Baranowski Daniel,Jakubowska Paulina,Klapiszewski ŁukaszORCID,Jesionowski TeofilORCID,Voelkel Adam,Strzemiecka Beata

Abstract

A series of cresol-based benzoxazines were synthesized for potential application as a polymer matrix in abrasive composites. The chemical structures of the obtained benzoxazine resins were investigated in detail using Fourier transform infrared spectroscopy (FTIR) and hydrogen-1 as well as carbon-13 nuclear magnetic resonance spectroscopy (1H NMR, 13C NMR) with an additional analysis using two-dimensional NMR techniques (2D NMR 1H-1H COSY, 1H-13C gHSQC and gHMBC). Structural analysis confirmed the presence of vibrations of -O-C-N- at ~950 cm−1 wavenumber, characteristic for an oxazine ring. The thermal properties of benzoxazine monomers were examined using differential scanning calorimetry (DSC) analysis. The polymerization enthalpy varied from 143.2 J/g to 287.8 J/g. Thermal stability of cresol-based benzoxazines was determined using thermogravimetry (TGA) analysis with additional analysis of the amount of volatile organic compounds (VOC) emitted from the synthesized benzoxazines during their crosslinking by static headspace coupled with gas chromatography technique (HS-GC). The amount of residual mass significantly differed between all synthesized polybenzoxazines in the range from 8.4% to 21.2%. The total VOC emission for benzoxazines decreased by 46–77% in reference to a conventional phenolic binder. The efficiency of abrasive composites with the benzoxazine matrix was evaluated based on abrasion tests. Performed analyses confirmed successful synthesis and proper chemical structure of cresol-based benzoxazines. All the experiments indicated that benzoxazines based on different cresol isomers significantly differ from each other. Good thermal performance and stability of the abrasive composites with the polybenzoxazine matrix and significantly lower VOC emission allow us to state that benzoxazines can be a promising and valuable alternative to the phenolics and a new path for the development of modern, eco-friendly abrasives.

Funder

Narodowe Centrum Nauki

Publisher

MDPI AG

Subject

General Materials Science

Reference40 articles.

1. Grinding Technology: Theory and Application of Machining with Abrasives;Malkin,2008

2. Modern Tribology Handbook;Bhushan,2000

3. Machining with Abrasives;Jackson,2011

4. Abrasives and Abrasive Wheels, Their Nature, Manufacture and Use: A Complete Treatise on the Manufacture and Practical Use of Abrasives, Abrasive Wheels and Grinding Operations;Jacobs,2017

5. Phenolic Resins: A Century of Progress;Pilato,2010

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