Affiliation:
1. State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
2. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China
Abstract
Liquid-liquid extraction is an important separation technology in the chemical industry, and its separation efficiency depends on thermodynamics (two-phase equilibrium), hydrodynamics (two-phase mixing and contact), and mass transfer (molecular diffusion). For hydrodynamics, the dispersion size of droplets reflects the mixing of two phases and determines the mass transfer contact area of the two phases. Therefore, a deep understanding of the droplet dispersion mechanism can help guide process intensification. The mass transfer and droplet behaviors in the liquid-liquid extraction process are reviewed based on three scales: equipment, droplets, and the interface between two liquids. Studies on the interaction between mass transfer and other performance parameters in extraction equipment as well as liquid-liquid two-phase flow models are reviewed at the equipment scale. The behaviors of droplet breakage and coalescence and the kernel function of the population balance equation are reviewed at the droplet scale. Studies on dynamic interfacial tension and interaction between interfaces are reviewed at the interface scale. Finally, the connection among each scale is summarized, the existing problems are analyzed, and some future research directions are proposed in the last section.
Funder
the National Natural Science Foundation of China
Subject
Filtration and Separation,Analytical Chemistry
Cited by
1 articles.
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