Treatment of Polycyclic Aromatic Hydrocarbons in Oil Sands Process-Affected Water with a Surface Flow Treatment Wetland

Abstract

This study applied a passive sampling approach using low-density polyethylene passive samplers to determine the treatment efficiency of the Kearl surface flow treatment wetland for polycyclic aromatic hydrocarbons (PAHs) in Oil Sands Process-affected Waters (OSPW). Treatment efficiency was measured as concentration-reduction and mass-removal from the OSPW. The results show that the wetland’s ability to remove individual PAHs from the influent varied substantially among the PAHs investigated. Treatment efficiencies of individual PAHs ranged between essentially 0% for certain methylated PAHs (e.g., 2,6-dimethylnaphthalene) to 95% for fluoranthene. Treatment in the Kearl wetland reduced the combined total mass of all detected PAHs by 54 to 83%. This corresponded to a reduction in the concentration of total PAHs in OSPW of 56 to 82% with inflow concentrations of total PAHs ranging from 7.5 to 19.4 ng/L. The concentration of pyrene in water fell below water quality targets in the Muskeg River Interim Management Framework as a result of wetland treatment. The application of the passive samplers for toxicity assessment showed that in this study PAHs in both the influent and effluent were not expected to cause acute toxicity. Passive sampling appeared to be a useful and cost-effective method for monitoring contaminants and for determining the treatment efficiency of contaminants in the treatment wetland.