Enhancing Flame Retardancy and Smoke Suppression in Epoxy Resin Composites with Sulfur–Phosphorous Reactive Flame Retardant

Author:

Ma Xulong1,Kang Ni1,Zhang Yonghang1,Min Yang1,Yang Jianhua1,Ban Daming1ORCID,Zhao Wei2ORCID

Affiliation:

1. School of Chemistry and Materials Science, Guizhou Normal University, Guiyang 550001, China

2. Technology and Engineering Center for Space Utilization, Chinese Academy of Sciences, Beijing 100094, China

Abstract

The presence of massive amounts of toxic volatiles and smoke during combustion is a very serious problem facing epoxy resin (EP) composites. Therefore, flame retardants (FRs) can simultaneously enhance flame retardancy and reduce the release of smoke and fatal gases. Herein, a novel sulfur–phosphorous reactive flame retardant (SPMS) was synthesized for epoxy resin. The high efficiency of smoke suppression and flame retardancy of the EP/SPMS-APP hybrid was investigated using a cone calorimeter, a vertical burning test, and limited oxygen index measurements. Compared with those of pure EP, the composite with 20 wt% SPMS-APP reduced the peak heat release rate (pHRR), the peak smoke production rate (SPR), and total smoke production rate (TSR) by 82%, 94%, and 84%, respectively. The results showed a remarkable suppressed effect of alleviating the fire hazard of EP using a sulfur–phosphorus flame retardant.

Funder

National Natural Science Foundation of China

Guiyang Science Project

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

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