Realizing Ultrafast and Robust Sodium-Ion Storage of Iron Sulfide Enabled by Heteroatomic Doping and Regulable Interface Engineering
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Published:2023-04-27
Issue:9
Volume:28
Page:3757
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ISSN:1420-3049
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Container-title:Molecules
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language:en
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Short-container-title:Molecules
Author:
Shen Jinke12, Wu Naiteng2, Xie Wei2, Li Qing2, Guo Donglei2ORCID, Li Jin2, Liu Guilong2ORCID, Liu Xianming2, Mi Hongyu1
Affiliation:
1. State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources, School of Chemical Engineering and Technology, Xinjiang University, Urumqi 830017, China 2. Key Laboratory of Green Energy Materials of Luoyang, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China
Abstract
Fe-based sulfides are a promising type of anode material for sodium-ion batteries (SIBs) due to their high theoretical capacities and affordability. However, these materials often suffer from issues such as capacity deterioration and poor conductivity during practical application. To address these challenges, an N-doped Fe7S8 anode with an N, S co-doped porous carbon framework (PPF-800) was synthesized using a template-assisted method. When serving as an anode for SIBs, it delivers a robust and ultrafast sodium storage performance, with a discharge capacity of 489 mAh g−1 after 500 cycles at 5 A g−1 and 371 mAh g−1 after 1000 cycles at 30 A g−1 in the ether-based electrolyte. This impressive performance is attributed to the combined influence of heteroatomic doping and adjustable interface engineering. The N, S co-doped carbon framework embedded with Fe7S8 nanoparticles effectively addresses the issues of volumetric expansion, reduces the impact of sodium polysulfides, improves intrinsic conductivity, and stimulates the dominant pseudocapacitive contribution (90.3% at 2 mV s−1). Moreover, the formation of a stable solid electrolyte interface (SEI) film by the effect of uniform pore structure in ether-based electrolyte produces a lower transfer resistance during the charge–discharge process, thereby boosting the rate performance of the electrode material. This work expands a facile strategy to optimize the electrochemical performance of other metal sulfides.
Funder
Natural Science Foundations of China Natural Science Foundations of Henan Province Universities of Henan Province Key Science and Technology Program of Henan Province Shanghai Cooperation Organization Project
Subject
Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science
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