A Visual Color Response Test Paper for the Detection of Hydrogen Sulfide Gas in the Air

Author:

Zhang Hailong1,Li Shiyu1,Zheng Hongpeng1,Han Zhongzhi2,Lin Bing1,Wang Yingying3,Guo Xiaojun2,Zhou Taigang1,Zhang Haibing4,Wu Jianjun5,Zhang Hui1,Tang Junlei1ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering & Institute for Carbon Neutrality, Southwest Petroleum University, Chengdu 610500, China

2. CNPC Engineering Technology Research Company Limited, Tianjin 300451, China

3. Key Laboratory of Optoelectronic Chemical Materials and Devices (Ministry of Education), Jianghan University, Wuhan 430056, China

4. State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao 266237, China

5. Research Institute of Tianfu New Energy, Chengdu 610217, China

Abstract

Hydrogen sulfide (H2S) is widely found in oil and natural gas wells and industrial wastewater tanks. Owing to its high toxicity, the monitoring and detection of H2S in the air is essential. However, recent techniques for the quantitative detection of H2S gas suffer from limitations such as high cost, complicated operation, and insufficient sensitivity, preventing their practical application in industry. Thus, we have developed a portable test paper for real-time and inexpensive monitoring of H2S gas by color changes. The test paper had a significantly low H2S detection limit of 200 ppb, which is considered safe for humans. Moreover, the color of the test paper did not change noticeably when exposed to CO2, N2, O2, and air environments, indicating that the test paper is selective for H2S gas and can be stored for a long time. In addition, we fitted a color difference linear model between the color difference values (ΔE) and the concentrations of H2S gas. The establishment of the linear model substantiates that the test paper can provide accurate intensity information when detecting H2S gas leakage.

Funder

central government to guide the development of local science and technology in Sichuan Province

Sichuan Science and Technology Program

PetroChina Key technical research on Marine oil and gas development and engineering

Liaoning Provincial Doctoral Research Foundation of 2021

2020 Post Doctor Scientific Research Special Foundation of Department of Human Resources and Social Security of Sichuan Province, China

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

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