Photoredox-Catalyzed Synthesis of 3-Sulfonylated Pyrrolin-2-ones via a Regioselective Tandem Sulfonylation Cyclization of 1,5-Dienes-Reference-Cited by-同舟云学术

Photoredox-Catalyzed Synthesis of 3-Sulfonylated Pyrrolin-2-ones via a Regioselective Tandem Sulfonylation Cyclization of 1,5-Dienes

Published:2023-07-17 Issue:14 Volume:28 Page:5473
ISSN:1420-3049
Container-title:Molecules
language:en
Short-container-title:Molecules

Author:

Ding Ran¹,Li Liang¹,Yu Ya-Ting¹,Zhang Bing¹,Wang Pei-Long²³^ORCID

Affiliation:

1. College of Chemistry and Materials Engineering, Anhui Science and Technology University, Bengbu 233100, China

2. Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education, School of Chemistry and Materials Science, Huaibei Normal University, Huaibei 235000, China

3. Information College, Huaibei Normal University, Huaibei 235000, China

Abstract

A mild, visible-light-induced, regioselective cascade sulfonylation-cyclization of 1,5-dienes with sulfonyl chlorides through the intermolecular radical addition/cyclization of alkenes C(sp2)-H was developed. This procedure proceeds well and affords a mild and efficient route to a range of monosulfonylated pyrrolin-2-ones at room temperatures.

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

Link

https://www.mdpi.com/1420-3049/28/14/5473/pdf

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