Abstract
A visible-light-induced external catalyst-free decarboxylation of dioxazolones was realized for the bond formation of N=P and N–C bonds to access phosphinimidic amides and ureas. Various phosphinimidic amides and ureas (47 examples) were synthesized with high yields (up to 98%) by this practical strategy in the presence of the system’s ppm Fe.
Funder
National Natural Science Foundation of China
Hunan Provincial Natural Science Foundation of China
Subject
Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science
Cited by
6 articles.
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