Abstract
The preparation of 24-functionalized 12,22:26,32-terpyridines (4′-functionalized 3,2:6′,3″-terpyridines) by the reaction of three 4-alkoxybenzaldehydes with 3-acetylpyridine and ammonia was investigated; under identical reaction conditions, two (R =nC4H9, C2H5) gave the expected products whereas a third (R = nC3H7) gave only a cyclohexanol derivative derived from the condensation of three molecules of 3-acetylpyridine with two of 4-(n-propoxy)benzaldehyde. A comprehensive survey of “unexpected” products from reactions of ArCOCH3 derivatives with aromatic aldehydes is presented. Three different types of alternative product are identified.
Subject
Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science
Reference81 articles.
1. Nomenclature of Organic Chemistry. IUPAC Recommendations and Preferred Names 2013;Favre,2013
2. Modern Terpyridine Chemistry;Schubert,2006
3. Terpyridine-Based Materials: For Catalytic, Optoelectronic and Life Science Applications;Schubert,2011
4. 2,2′:6′,2″-Terpyridines: From chemical obscurity to common supramolecular motifs
5. Terpyridine-metal complexes: Applications in catalysis and supramolecular chemistry
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