Self-Healing Properties of Water Tree Damage in Multilayered Shell–Core-Structured Microcapsules/Cross-Linked Polyethylene Composites
Author:
Zhu Bo1, Sun Hao1, Zhu Yaqi1, He Shengkun1, Han Ximu1
Affiliation:
1. MOE Key Laboratory of Engineering Dielectrics and Its Application, Harbin University of Science and Technology, Harbin 150080, China
Abstract
To investigate the effect of the structure of microcapsules on the properties of cross-linked polyethylene (XLPE) composites, three XLPE specimens filled with multilayered shell–core-structured microcapsules are designed. In this paper, the microcapsules are first analyzed morphologically and chemically. In addition, the effect of the microcapsule structure on the typical electrical properties of the composites is explored. Finally, the self-healing ability of XLPE specimens filled with microcapsules is verified. The results show that the SiO2 on the surface of the trilayer shell–core microcapsules can make the microcapsules and the XLPE matrix have a better mechanical interlocking ability, which makes the typical properties of the trilayer shell–core microcapsules slightly better than those of the bilayer shell–core microcapsules. Moreover, when the bilayer shell–core or trilayer shell–core microcapsules rupture under the action of an electric field, the repair material reacts with the water tree under capillary action to consume the residual water while generating organic matter to fill in the cavity, thus repairing the damaged area of the water tree and ultimately achieving the self-healing of the composite water tree.
Funder
Basic Research Support Program for Excellent Young Teachers in the Provincial Universities of Heilongjiang Province, China
Subject
Polymers and Plastics,General Chemistry
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