High-Throughput Synthesis and Characterization Screening of Mg-Cu-Y Metallic Glass

Abstract

Bulk metallic glasses can exhibit novel material properties for engineering scale components, but the experimental discovery of new alloy compositions is time intensive and thwarts the rate of discovery. This study presents an experimental, high-throughput methodology to increase the speed of discovery for potential bulk metallic glass alloys. A well-documented system, Mg-Cu-Y, was used as a model system. A laser additive manufacturing technique, directed energy deposition, was used for the in situ alloying of elemental powders to synthesize discrete compositions in the ternary system. The laser processing technique can supply the necessary cooling rates of 103–104 Ks−1 for bulk metallic glass formation. The in situ alloying enables the rapid synthesis of compositional libraries with larger sample sizes and discrete compositions than are provided by combinatorial thin films. Approximately 1000 discrete compositions can be synthesized in a day. Surface smoothness, as discerned by optical reflectivity, can suggest glass-forming alloys. X-ray diffraction coupled with energy dispersive X-ray spectroscopy can further refine amorphous alloy signatures and compositions. Transmission electron microscopy confirms amorphous samples. The tiered rate of amorphous alloy synthesis and characterization can survey a large compositional space and permits a glass-forming range to be identified within one week, making the process at least three orders of magnitude faster than other discrete composition techniques such as arc-melting or melt-spinning.