Observations by Ground-Based MAX-DOAS of the Vertical Characters of Winter Pollution and the Influencing Factors of HONO Generation in Shanghai, China

Abstract

Analyzing vertical distribution characters of air pollutants is conducive to study the mechanisms under polluted atmospheric conditions. Nitrous acid (HONO) is a kind of crucial species in photochemical cycles. Exploring the influence and sources of HONO in air pollution at different altitudes offers some insights into the research of tropospheric oxidation chemistry processes. Ground-based multi-axis differential optical absorption spectroscopy (MAX-DOAS) measurements were conducted in Shanghai, China, from December 2017 to March 2018 to investigate vertical distributions and diurnal variations of trace gases (NO2, HONO, HCHO, SO2, and water vapor) and aerosol extinction coefficient in the boundary layer. Aerosol and NO2 showed decreasing profile exponentially, SO2 and HCHO concentrations were observed relatively high values in the middle layer. SO2 was caused by industrial emissions, while HCHO was from secondary sources. As for HONO, below 0.82 km, the heterogeneous reactions of NO2 impacted on forming HONO, while in the upper layers, vertical diffusion might be the dominant source. The contribution of OH production from HONO photolysis at different altitudes was mainly controlled by the concentration of HONO. MAX-DOAS measurements characterize the vertical structure of air pollutants in Shanghai and provide further understanding for HONO formation, which can help deploy advanced measurement platforms of regional air pollution over eastern China.