Ammonia Emissions in SI Engines Fueled with LPG

Abstract

Ammonia is a toxic exhaust component emitted from internal combustion engines. Both pure ammonia and the products of its reaction with nitrogen and sulfur compounds, being the source of particulate matter (PM) emissions, are dangerous for human health and life. The aim of the article was to demonstrate that NH3 can be produced in exhaust gas after-treatment systems of spark-ignition (SI) engines used in light-duty vehicles. In some cases, NH3 occurs in high enough concentrations that can be harmful and dangerous. It would be reasonable to collect research data regarding this problem and consider the advisability of limiting these pollutant emissions in future regulations. The article presents the results of the spark-ignition engine testing on an engine test bench and discusses the impact of the air–fuel ratio regulation and some engine operating parameters on the concentration of NH3. It has been proven that in certain engine operating conditions and a combination of circumstances like the three-way catalytic reactor (TWC) temperature and periodic enrichment of the air–fuel mixture may lead to excessive NH3 emissions resulting from the NO conversion in the catalytic reactor. This is a clear disadvantage due to the lack of limitation of these pollutant emissions by the relevant type-approval regulations. This article should be a contribution to discussion among emissions researchers whether future emission regulations (e.g., Euro 7 or Euro VII) should include a provision to reduce NH3 emissions from all vehicles.