Adsorptive Membranes Incorporating Ionic Liquids (ILs), Deep Eutectic Solvents (DESs) or Graphene Oxide (GO) for Metal Salts Extraction from Aqueous Feed

Abstract

Water scarcity is a significant concern, particularly in arid regions, due to the rapid growth in population, industrialization, and climate change. Seawater desalination has emerged as a conventional and reliable solution for obtaining potable water. However, conventional membrane-based seawater desalination has drawbacks, such as high energy consumption resulting from a high-pressure requirement, as well as operational challenges like membrane fouling and high costs. To overcome these limitations, it is crucial to enhance the performance of membranes by increasing their efficiency, selectivity, and reducing energy consumption and footprint. Adsorptive membranes, which integrate adsorption and membrane technologies, offer a promising approach to address the drawbacks of standalone membranes. By incorporating specific materials into the membrane matrix, composite membranes have demonstrated improved permeability, selectivity, and reduced pressure requirements, all while maintaining effective pollutant rejection. Researchers have explored different adsorbents, including emerging materials such as ionic liquids (ILs), deep eutectic solvents (DESs), and graphene oxide (GO), for embedding into membranes and utilizing them in various applications. This paper aims to discuss the existing challenges in the desalination process and focus on how these materials can help overcome these challenges. It will also provide a comprehensive review of studies that have reported the successful incorporation of ILs, DESs, and GO into membranes to fabricate adsorptive membranes for desalination. Additionally, the paper will highlight both the current and anticipated challenges in this field, as well as present prospects, and provide recommendations for further advancements.